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Beilstein J. Org. Chem. 2009, 5, No. 74, doi:10.3762/bjoc.5.74
Graphical Abstract
Figure 1: Conformationally flexible 3, 4-bridged dithia-thienothiophenophanes.
Scheme 1: Synthetic scheme for compounds 7, 9 and 11.
Figure 2: ORTEP plot of the crystal structure of 11. Important parameters: Bond length (Å) : C8–C9 = 1.492, C...
Scheme 2: Computed three most stable conformations of 11 and their calculated energies.